Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination

Paramagnetic dithiolene complexes as metallo-ligands: ether/thioether coordination.

The secondary coordination ability of a paramagnetic nickel dithiolene complex, bearing an ether coordinating function within a nine-membered flexible ring, has been demonstrated in its [NiCl(DMF)(2)](+) complex, through coordination by both ether and thioether functions, allowing for a ferromagnetic interaction between both paramagnetic entities.

Dithiolene complexes as metallo-ligands: a crown-ether approach

The contrasted structural and magnetic behaviour of two single-component paramagnetic dithiolene complexes

The neutral organometallic/dithiolene radical complexes [CpNi(oxddt)] and [CpNi(bddt)] were prepared, respectively, from the reactions of [Ni(oxddt)2] with [Cp2Ni] and (NBu4)[Ni(bddt)2] with [CpNi(cod)](BF4) (oxddt = o-xylenediyldithioethylene-1,2-dithiolato, bddt = 1,4butanediyldithioethylene-1,2-dithiolato). Both complexes exhibit reversible oxidation and reduction waves to the cation and ani...

Water-soluble nickel-bis(dithiolene) complexes as photothermal agents.

The remarkable photothermal properties of pegylated nickel-bis(dithiolene) complexes in water can induce cell death under laser irradiation in the near infrared (NIR) region.

Coordination Complexes as Catalysts

Coordination Complexes as Catalysts The first half of the book focuses on the use of coordination complexes as catalysts for a diverse range of organic reactions. Chapters on supported metal complexes and combinatorial catalysis are also included in this half of the book. Chapter 1, covering catalysts for polymerisation, is not an area where platinum group metal (pgm) complexes would be expecte...